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Two workers were injured in an explosion at the Cardón refinery in Venezuela's northwestern state of Falcón, according to a labor union.
The incident occurred at the facility's naphtha reformer on Tuesday night, the federation of petroleum workers (FTPV) said.
According to FTPV representative Yván Freites, the workers were trying to light one of the furnaces, which had been deactivated for five months.
The victims, one of whom suffered second and third degree burns, were taken to hospital for treatment, according to local newspaper La Verdad.
The Cardón plant forms part of the Paraguaná refinery complex, one of the largest in the world with capacity of 955,000b/d.
State-run oil company PDVSA, which operates the complex, did not comment on the incident.